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Diruthenium Tetracarboxylate-Catalyzed Enantioselective Cyclopropanation with Aryldiazoacetates

[Image: see text] A series of chiral bowl-shaped diruthenium(II,III) tetracarboxylate catalysts were prepared and evaluated in asymmetric cyclopropanations with donor/acceptor carbenes derived from aryldiazoacetates. The diruthenium catalysts self-assembled to generate C(4)-symmetric bowl-shaped str...

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Detalles Bibliográficos
Autores principales: Sailer, Joshua K., Sharland, Jack C., Bacsa, John, Harris, Caleb F., Berry, John F., Musaev, Djamaladdin G., Davies, Huw M. L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428512/
https://www.ncbi.nlm.nih.gov/pubmed/37592951
http://dx.doi.org/10.1021/acs.organomet.3c00268