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Exploring the role of halogen bonding in iodonium ylides: insights into unexpected reactivity and reaction control

Halogen bonding is commonly found with iodine-containing molecules, and it arises when Lewis bases interact with iodine’s σ-holes. Halogen bonding and σ-holes have been encountered in numerous monovalent and hypervalent iodine-containing compounds, and in 2022 σ-holes were computationally confirmed...

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Detalles Bibliográficos
Autores principales: Montgomery, Carlee A, Murphy, Graham K
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10428621/
https://www.ncbi.nlm.nih.gov/pubmed/37592937
http://dx.doi.org/10.3762/bjoc.19.86