Rare earth dialkyl cations and monoalkyl dications supported by a rigid neutral pincer ligand: synthesis and ethylene polymerization

A palladium-catalyzed coupling reaction between 4,5-dibromo-2,7-di-tert-butyl-9,9-dimethylxanthene and 2 equiv. of 1,3-diisopropylimidazolin-2-imine afforded the rigid neutral 2,7-di-tert-butyl-4,5-bis(1,3-diisopropylimidazolin-2-imino)-9,9-dimethylxanthene (XII(2)) pincer ligand. Reaction of XII(2)...

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Detalles Bibliográficos
Autores principales: Vasanthakumar, Aathith, Price, Jeffrey S., Emslie, David J. H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430518/
https://www.ncbi.nlm.nih.gov/pubmed/37592999
http://dx.doi.org/10.1039/d3sc01830j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430518/
https://www.ncbi.nlm.nih.gov/pubmed/37592999
http://dx.doi.org/10.1039/d3sc01830j

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