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Salt-stabilized alkylzinc pivalates: versatile reagents for cobalt-catalyzed selective 1,2-dialkylation

The construction of Csp(3)–Csp(3) bonds through Negishi-type reactions using alkylzinc reagents as the pronucleophiles is of great importance for the synthesis of pharmaceuticals and agrochemicals. However, the use of air and moisture sensitive solutions of conventional alkylzinc halides, which show...

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Detalles Bibliográficos
Autores principales: Lin, Jie, Chen, Kaixin, Wang, Jixin, Guo, Jiawei, Dai, Siheng, Hu, Ying, Li, Jie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430519/
https://www.ncbi.nlm.nih.gov/pubmed/37592988
http://dx.doi.org/10.1039/d3sc02345a