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Nitrogen Trifluoride Complexes of Group 10 Transition Metals M(NF(3)) (M = Pd, Pt)
The group 10 transition metal atoms Pd and Pt react with nitrogen trifluoride (NF(3)) forming N-coordination M(NF(3)) complexes in solid neon and argon matrices. The M(NF(3)) complexes isomerize to more stable fluoronitrenoid FNMF(2) isomers via fluorine migration upon blue LED (λ = 470 nm) light ir...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430601/ https://www.ncbi.nlm.nih.gov/pubmed/37593001 http://dx.doi.org/10.1039/d3sc02313c |