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Nitrogen Trifluoride Complexes of Group 10 Transition Metals M(NF(3)) (M = Pd, Pt)

The group 10 transition metal atoms Pd and Pt react with nitrogen trifluoride (NF(3)) forming N-coordination M(NF(3)) complexes in solid neon and argon matrices. The M(NF(3)) complexes isomerize to more stable fluoronitrenoid FNMF(2) isomers via fluorine migration upon blue LED (λ = 470 nm) light ir...

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Detalles Bibliográficos
Autores principales: Deng, Guohai, Lu, Yan, Stüker, Tony, Riedel, Sebastian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430601/
https://www.ncbi.nlm.nih.gov/pubmed/37593001
http://dx.doi.org/10.1039/d3sc02313c

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