Rhodium-catalyzed annulative approach to N–N axially chiral biaryls via C–H activation and dynamic kinetic transformation

N–N axially chiral biaryls represent a rarely explored class of atropisomeric compounds. We hereby report rhodium-catalyzed enantioselective [4 + 2] oxidative annulation of internal alkynes with benzamides bearing two classes of N–N directing groups. The coupling occurs under mild conditions via NH...

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Detalles Bibliográficos
Autores principales: Zhu, Xiaohan, Wu, Hongli, Wang, Yishou, Huang, Genping, Wang, Fen, Li, Xingwei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430736/
https://www.ncbi.nlm.nih.gov/pubmed/37592987
http://dx.doi.org/10.1039/d3sc02800c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10430736/
https://www.ncbi.nlm.nih.gov/pubmed/37592987
http://dx.doi.org/10.1039/d3sc02800c

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