Cycloaddition and C–S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate

[Image: see text] Reactions of [MoReCp(μ-PMes*)(CO)(6)] with internal alkynes RC≡CR yielded the phosphapropenylidene-bridged complexes [MoReCp(μ-κ(2)(P,C):η(3)-PMes*CRCR)(CO)(5)] (Mes* = 2,4,6-C(6)H(2)(t)Bu(3); R = CO(2)Me, Ph). Terminal alkynes HC≡CR(1) gave mixtures of isomers [MoReCp(μ-κ(2)(P,C):...

Descripción completa

Detalles Bibliográficos
Autores principales: Alvarez, M. Angeles, García, M. Esther, García-Vivó, Daniel, Ruiz, Miguel A., Vega, Patricia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10431387/
https://www.ncbi.nlm.nih.gov/pubmed/37592950
http://dx.doi.org/10.1021/acs.organomet.3c00242

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10431387/
https://www.ncbi.nlm.nih.gov/pubmed/37592950
http://dx.doi.org/10.1021/acs.organomet.3c00242

Ejemplares similares