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Cycloaddition and C–S Bond Cleavage Processes in Reactions of Heterometallic Phosphinidene-Bridged MoRe and MoMn Complexes with Alkynes and Phenyl Isothiocyanate
[Image: see text] Reactions of [MoReCp(μ-PMes*)(CO)(6)] with internal alkynes RC≡CR yielded the phosphapropenylidene-bridged complexes [MoReCp(μ-κ(2)(P,C):η(3)-PMes*CRCR)(CO)(5)] (Mes* = 2,4,6-C(6)H(2)(t)Bu(3); R = CO(2)Me, Ph). Terminal alkynes HC≡CR(1) gave mixtures of isomers [MoReCp(μ-κ(2)(P,C):...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10431387/ https://www.ncbi.nlm.nih.gov/pubmed/37592950 http://dx.doi.org/10.1021/acs.organomet.3c00242 |