Synthesis and crystal structure of a bench-stable pyridinium ketene hemiaminal: 1-(1-eth­oxy­ethen­yl)-2-[meth­yl(phen­yl)amino]­pyridin-1-ium tri­fluoro­methane­sulfonate

The novel bench-stable N-quaternized ketene N,O-acetal, C(16)H(19)N(2)O(+)·CF(3)O(3)S(−), was synthesized and its structure determined. The title compound is a rare example of a pyridinium ketene hemiaminal for which a crystal structure has been determined, joining the 2-chloro-1-(1-ethyoxyethen­yl)...

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Detalles Bibliográficos
Autores principales: Krevlin, Zoe A., Bote, Isabella C., Crespo, Maria Christina F., Lam, Christie C., McMillen, Colin D., Majireck, Max M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439406/
https://www.ncbi.nlm.nih.gov/pubmed/37601406
http://dx.doi.org/10.1107/S2056989023005741

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439406/
https://www.ncbi.nlm.nih.gov/pubmed/37601406
http://dx.doi.org/10.1107/S2056989023005741

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