Regio- and enantioselective CuH-catalyzed 1,2- and 1,4-hydrosilylation of 1,3-enynes

We report a copper-catalyzed ligand-controlled selective 1,2- and 1,4-hydrosilylation of 1,3-enynes, which furnishes enantiomerically enriched propargyl- and 1,2-allenylsilane products in high yields with excellent enantioselectivities (up to 99% ee). This reaction proceeds under mild conditions, sh...

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Detalles Bibliográficos
Autores principales: Wang, Zi-Lu, Li, Qi, Yang, Meng-Wei, Song, Zhao-Xin, Xiao, Zhen-Yu, Ma, Wei-Wei, Zhao, Jin-Bo, Xu, Yun-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439940/
https://www.ncbi.nlm.nih.gov/pubmed/37598226
http://dx.doi.org/10.1038/s41467-023-40703-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10439940/
https://www.ncbi.nlm.nih.gov/pubmed/37598226
http://dx.doi.org/10.1038/s41467-023-40703-1

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