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Microwave-Assisted Palladium Acetate-Catalyzed C–P Cross-Coupling of Arylboronic Acids and >P(O)H Reagents in the Absence of the Usual Mono- and Bidentate P-Ligands: Mechanistic Insights

[Image: see text] A less-studied halogen-free variation of the Hirao reaction involving the coupling of arylboronic acids with >P(O)H reagents, such as diarylphosphine oxides, diethyl phosphite, and ethyl phenyl-H-phosphinate, was investigated in detail using Pd(OAc)(2) as the catalyst precursor...

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Detalles Bibliográficos
Autores principales: Huszár, Bianka, Mucsi, Zoltán, Keglevich, György
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10442920/
https://www.ncbi.nlm.nih.gov/pubmed/37556619
http://dx.doi.org/10.1021/acs.joc.3c01269