Reactivity of ethyl nitrosoacrylate toward pyrrole, indole and pyrrolo[3,2-c]carbazole: an experimental and theoretical study

Nitrosoalkenes react with 8-methyl-1,6-dihydropyrrolo[3,2-c]carbazole to give both 2- and 3-alkylated products via hetero-Diels-Alder reaction followed by the cycloadduct ring-opening. Quantum chemical calculations, at DFT level of theory, were carried out to investigate the regioselectivity of the...

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Detalles Bibliográficos
Autores principales: Benzi, Alice, Lopes, Susana M. M., Nunes, Sandra C. C., Giorgi, Gianluca, Bianchi, Lara, Tavani, Cinzia, Pais, Alberto A. C. C., Petrillo, Giovanni, Pinho e Melo, Teresa M. V. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10443595/
https://www.ncbi.nlm.nih.gov/pubmed/37614704
http://dx.doi.org/10.3389/fchem.2023.1229669

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10443595/
https://www.ncbi.nlm.nih.gov/pubmed/37614704
http://dx.doi.org/10.3389/fchem.2023.1229669

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