Significance of the connecting position between Zn(ii) porphyrin and Re(i) bipyridine tricarbonyl complex units in dyads for room-temperature phosphorescence and photocatalytic CO(2) reduction: unexpected enhancement by triethanolamine in catalytic activity

We synthesized three new dyads composed of a Zn porphyrin and fac-Re(bpy)(CO)(3)Br (bpy = 2,2′-bipyridine) units, ZnP-nBpy[double bond, length as m-dash]Re(Br) (n = 4, 5, and 6), in which the porphyrin is directly connected at the meso-position through the 4-, 5-, or 6-position of the bpy. We invest...

Descripción completa

Detalles Bibliográficos
Autores principales: Kuramochi, Yusuke, Suzuki, Yuto, Asai, Somyo, Suzuki, Tomohiro, Iwama, Hiroki, Asano, Motoko S., Satake, Akiharu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445468/
https://www.ncbi.nlm.nih.gov/pubmed/37621430
http://dx.doi.org/10.1039/d3sc02430j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445468/
https://www.ncbi.nlm.nih.gov/pubmed/37621430
http://dx.doi.org/10.1039/d3sc02430j

Ejemplares similares