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Significance of the connecting position between Zn(ii) porphyrin and Re(i) bipyridine tricarbonyl complex units in dyads for room-temperature phosphorescence and photocatalytic CO(2) reduction: unexpected enhancement by triethanolamine in catalytic activity
We synthesized three new dyads composed of a Zn porphyrin and fac-Re(bpy)(CO)(3)Br (bpy = 2,2′-bipyridine) units, ZnP-nBpy[double bond, length as m-dash]Re(Br) (n = 4, 5, and 6), in which the porphyrin is directly connected at the meso-position through the 4-, 5-, or 6-position of the bpy. We invest...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445468/ https://www.ncbi.nlm.nih.gov/pubmed/37621430 http://dx.doi.org/10.1039/d3sc02430j |