Cargando…

Planar pentacoordinate s-block metals

The presence of a delocalized π-bond is often considered an essential criterion for achieving planar hypercoordination. Herein, we show that σ-delocalization could be sufficient to make the planar configuration the most stable isomer in a series of planar pentacoordinate s-block metals. High-level a...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Meng-hui, Kalita, Amlan J., Orozco-Ic, Mesías, Yan, Gai-ru, Chen, Chen, Yan, Bing, Castillo-Toraya, Gabriela, Tiznado, William, Guha, Ankur K., Pan, Sudip, Merino, Gabriel, Cui, Zhong-hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445469/
https://www.ncbi.nlm.nih.gov/pubmed/37621437
http://dx.doi.org/10.1039/d2sc05939h