Cargando…

Planar pentacoordinate s-block metals

The presence of a delocalized π-bond is often considered an essential criterion for achieving planar hypercoordination. Herein, we show that σ-delocalization could be sufficient to make the planar configuration the most stable isomer in a series of planar pentacoordinate s-block metals. High-level a...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Meng-hui, Kalita, Amlan J., Orozco-Ic, Mesías, Yan, Gai-ru, Chen, Chen, Yan, Bing, Castillo-Toraya, Gabriela, Tiznado, William, Guha, Ankur K., Pan, Sudip, Merino, Gabriel, Cui, Zhong-hua
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10445469/ https://www.ncbi.nlm.nih.gov/pubmed/37621437 http://dx.doi.org/10.1039/d2sc05939h

Ejemplares similares

σ-Aromaticity in planar pentacoordinate aluminium and gallium clusters
por: Kalita, Amlan J., et al.
Publicado: (2022)

Planar tetracoordinate fluorine atoms
por: Castillo-Toraya, Gabriela, et al.
Publicado: (2021)

Nitrogen versus carbon in planar pentacoordinate environments supported by Be(5)H(n) rings
por: Bian, Jian-Hong, et al.
Publicado: (2021)

Stabilization of beryllium-containing planar pentacoordinate carbon species through attaching hydrogen atoms
por: Zhao, Xue-Feng, et al.
Publicado: (2018)

Chiral Hypervalent, Pentacoordinated Phosphoranes
por: Krasowska, Dorota, et al.
Publicado: (2016)

Semi-metallic Be(5)C(2) monolayer global minimum with quasi-planar pentacoordinate carbons and negative Poisson's ratio
por: Wang, Yu, et al.
Publicado: (2016)

Sulphur-Bridged BAl(5)S(5)(+) with 17 Counting Electrons: A Regular Planar Pentacoordinate Boron System
por: Ye, Yuhan, et al.
Publicado: (2021)

Delocalization in Substituted Benzene Dications: A Magnetic Point of View
por: Orozco‐Ic, Mesías, et al.
Publicado: (2020)

B(3)Al(4)(+): A Three-Dimensional Molecular Reuleaux Triangle
por: Bai, Li-Xia, et al.
Publicado: (2022)

The Diagnostic Vibrational Signature of Pentacoordination in Heme Carbonyls
por: Linder, Douglas P., et al.
Publicado: (2014)

Chiral Control in Pentacoordinate Systems: The Case of Organosilicates
por: van der Boon, Leon J. P., et al.
Publicado: (2018)

Theoretical Design of Stable Pentacoordinate Boron Compounds
por: Li, Zhipeng, et al.
Publicado: (2022)

Synthesis and properties of hypervalent electron-rich pentacoordinate nitrogen compounds
por: Yan, Chenting, et al.
Publicado: (2020)

Dispersion, Rehybridization, and Pentacoordination: Keys to Understand Clustering of Boron and Aluminum Hydrides and Halides
por: Mó, Otilia, et al.
Publicado: (2023)

Dual colorimetric sensing of ascorbic acid and thyroxine using Ag–EGCG–CTAB via a DFT approach
por: Borah, Nirangkush, et al.
Publicado: (2021)

Calculation of magnetic response properties of tetrazines
por: Orozco-Ic, Mesías, et al.
Publicado: (2020)

Atomically Dispersed Pentacoordinated‐Zirconium Catalyst with Axial Oxygen Ligand for Oxygen Reduction Reaction
por: Wang, Xia, et al.
Publicado: (2022)

A closer look into close packing: pentacoordinated silicon in a high-pressure polymorph of danburite
por: Pakhomova, Anna, et al.
Publicado: (2017)

Planar hexacoordinate gallium
por: Wang, Meng-hui, et al.
Publicado: (2021)

Disilanes with Pentacoordinate Si Atoms by Carbon Dioxide Insertion into Aminodisilanes: Syntheses, Molecular Structures, and Dynamic Behavior
por: Ryll, Christopher, et al.
Publicado: (2022)

Bare and ligand protected planar hexacoordinate silicon in SiSb(3)M(3)(+) (M = Ca, Sr, Ba) clusters
por: Chen, Chen, et al.
Publicado: (2022)

Highly sensitive and selective colorimetric detection of dual metal ions (Hg(2+) and Sn(2+)) in water: an eco-friendly approach
por: Paw, Rintumoni, et al.
Publicado: (2021)

Correction: Highly sensitive and selective colorimetric detection of dual metal ions (Hg(2+) and Sn(2+)) in water: an eco-friendly approach
por: Paw, Rintumoni, et al.
Publicado: (2022)

Pentacoordinated Organotin(IV) Complexes as an Alternative in the Design of Highly Efficient Optoelectronic and Photovoltaic Devices: Synthesis and Photophysical Characterization
por: Sánchez Vergara, María Elena, et al.
Publicado: (2023)

Distinctive structural properties of THB11, a pentacoordinate Chlamydomonas reinhardtii truncated hemoglobin with N- and C-terminal extensions
por: Huwald, Dennis, et al.
Publicado: (2020)

Oxidative Addition of Aryl Halides to a Triphosphine Ni(0) Center to Form Pentacoordinate Ni(II) Aryl Species
por: Pérez−García, Pablo M., et al.
Publicado: (2020)

An Innovative Structural Rearrangement in Imine Palladacycle Metaloligand Chemistry: From Single-Nuclear to Double-Nuclear Pseudo-Pentacoordinated Complexes
por: al Janabi, Basma, et al.
Publicado: (2023)

Unsupported Donor–Acceptor Complexes of Noble Gases with Group 13 Elements
por: Mazumder, Lakhya J., et al.
Publicado: (2021)

Pentacoordinate and Hexacoordinate Mn(III) Complexes of Tetradentate Schiff-Base Ligands Containing Tetracyanidoplatinate(II) Bridges and Revealing Uniaxial Magnetic Anisotropy
por: Nemec, Ivan, et al.
Publicado: (2016)

A Quantum Chemistry View on Two Archetypical Paramagnetic Pentacoordinate Nickel(II) Complexes Offers a Fresh Look on Their NMR Spectra
por: Ravera, Enrico, et al.
Publicado: (2021)

Assembly of planar chiral superlattices from achiral building blocks
por: Cheng, Zhihua, et al.
Publicado: (2022)

Broadband planar antennas: design and applications
por: Chen Zhi Ning, et al.
Publicado: (2006)

Planar Elongated B(12) Structure in M(3)B(12) Clusters (M = Cu-Au)
por: Solar-Encinas, José, et al.
Publicado: (2022)

Batrachotoxin-modified sodium channels in planar lipid bilayers. Ion permeation and block
Publicado: (1987)

Symposium on Powder Diffraction: Frontiers of Synchrotron Radiation Powder Diffraction
por: Toraya, H, et al.
Publicado: (1997)

Planar and Helical Dinaphthophenazines
por: Chen, Fengkun, et al.
Publicado: (2022)

Batrachotoxin-activated Na+ channels in planar lipid bilayers. Competition of tetrodotoxin block by Na+
Publicado: (1984)

High-Density Reconstitution of Functional Water Channels into Vesicular and Planar Block Copolymer Membranes
por: Kumar, Manish, et al.
Publicado: (2012)

Layer-By-Layer Self-Assembly of Polyelectrolytic Block Copolymer Worms on a Planar Substrate
por: Penfold, Nicholas J. W., et al.
Publicado: (2017)

Un siglo de cemento en Latinoamérica
por: Cuevas Toraya, Juan de las
Publicado: (1999)

Cannot write session to /tmp/vufind_sessions/sess_i08gccon5liojsujogbr4op4fq