Turning sulfonyl and sulfonimidoyl fluoride electrophiles into sulfur(VI) radicals for alkene ligation

Sulfonyl and sulfonimidoyl fluorides are versatile substrates in organic synthesis and medicinal chemistry. However, they have been exclusively used as S(VI)(+) electrophiles for defluorinative ligations. Converting sulfonyl and sulfonimidoyl fluorides to S(VI) radicals is challenging and underexplo...

Descripción completa

Detalles Bibliográficos
Autores principales: Wu, Xing, Zhang, Wenbo, Sun, Guangwu, Zou, Xi, Sang, Xiaoru, He, Yongmin, Gao, Bing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10449886/
https://www.ncbi.nlm.nih.gov/pubmed/37620301
http://dx.doi.org/10.1038/s41467-023-40615-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10449886/
https://www.ncbi.nlm.nih.gov/pubmed/37620301
http://dx.doi.org/10.1038/s41467-023-40615-0

Ejemplares similares