Cu(4)S Cluster in “0-Hole” and “1-Hole” States: Geometric and Electronic Structure Variations for the Active Cu(Z)* Site of N(2)O Reductase

[Image: see text] The active site of nitrous oxide reductase (N(2)OR), a key enzyme in denitrification, features a unique μ(4)-sulfido-bridged tetranuclear Cu cluster (the so-called Cu(Z) or Cu(Z)* site). Details of the catalytic mechanism have remained under debate and, to date, synthetic model com...

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Detalles Bibliográficos
Autores principales: Liu, Yang, Chatterjee, Sayanti, Cutsail, George E., Peredkov, Sergey, Gupta, Sandeep K., Dechert, Sebastian, DeBeer, Serena, Meyer, Franc
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10450684/
https://www.ncbi.nlm.nih.gov/pubmed/37565682
http://dx.doi.org/10.1021/jacs.3c04893

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10450684/
https://www.ncbi.nlm.nih.gov/pubmed/37565682
http://dx.doi.org/10.1021/jacs.3c04893

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