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Cu(4)S Cluster in “0-Hole” and “1-Hole” States: Geometric and Electronic Structure Variations for the Active Cu(Z)* Site of N(2)O Reductase
[Image: see text] The active site of nitrous oxide reductase (N(2)OR), a key enzyme in denitrification, features a unique μ(4)-sulfido-bridged tetranuclear Cu cluster (the so-called Cu(Z) or Cu(Z)* site). Details of the catalytic mechanism have remained under debate and, to date, synthetic model com...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10450684/ https://www.ncbi.nlm.nih.gov/pubmed/37565682 http://dx.doi.org/10.1021/jacs.3c04893 |