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Mechanochemical Phosphorylation of Acetylides Using Condensed Phosphates: A Sustainable Route to Alkynyl Phosphonates

[Image: see text] In pursuit of a more sustainable route to phosphorus–carbon (P–C) bond-containing chemicals, we herein report that phosphonates can be prepared by mechanochemical phosphorylation of acetylides using polyphosphates in a single step, redox-neutral process, bypassing white phosphorus...

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Detalles Bibliográficos
Autores principales: Xin, Tiansi, Cummins, Christopher C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10451036/
https://www.ncbi.nlm.nih.gov/pubmed/37637745
http://dx.doi.org/10.1021/acscentsci.3c00725