A Chiral Relay Race: Stereoselective Synthesis of Axially Chiral Biaryl Diketones through Ring-Opening of Optical Dihydrophenan-threne-9,10-diols

We report herein a point-to-axial chirality transfer reaction of optical dihydrophenanthrene-9,10-diols for the synthesis of axially chiral diketones. Two sets of conditions, namely a basic tBuOK/air atmosphere and an acidic NaClO/n-Bu(4)NHSO(4), were developed to oxidatively cleave the C-C bond, re...

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Detalles Bibliográficos
Autores principales: Shi, Lei, Zhu, Jiawei, Hong, Biqiong, Gu, Zhenhua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10459955/
https://www.ncbi.nlm.nih.gov/pubmed/37630207
http://dx.doi.org/10.3390/molecules28165956

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10459955/
https://www.ncbi.nlm.nih.gov/pubmed/37630207
http://dx.doi.org/10.3390/molecules28165956

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