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Stereoselective Palladium-Catalyzed C–F Bond Alkenylation of Tetrasubstituted gem-Difluoroalkenes via Mizoroki–Heck Reaction
[Image: see text] A highly diastereoselective Pd(0)-catalyzed Mizoroki–Heck reaction of gem-difluoroalkenes is described. Unlike previously reported C–F bond functionalization with organometallic reagents, this reaction takes place between two different alkenes to achieve a formal C–F and C–H bond c...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463225/ https://www.ncbi.nlm.nih.gov/pubmed/37584488 http://dx.doi.org/10.1021/acs.orglett.3c02452 |