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Ruthenium complexes of 1,4-diazabutadiene ligands with a cis-RuCl(2) moiety for catalytic acceptorless dehydrogenation of alcohols: DFT evidence of chemically non-innocent ligand participation
The acceptorless dehydrogenative coupling (ADC) of primary alcohols to esters by diazabutadiene-coordinated ruthenium compounds is reported. Treatment of cis-Ru(dmso)(4)Cl(2) in acetone at 56 °C with different 1,4-diazabutadienes [p-XC(6)H(4)N[double bond, length as m-dash]C(H)(H)C[double bond, leng...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463240/ https://www.ncbi.nlm.nih.gov/pubmed/37649575 http://dx.doi.org/10.1039/d3ra04750d |