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Ruthenium complexes of 1,4-diazabutadiene ligands with a cis-RuCl(2) moiety for catalytic acceptorless dehydrogenation of alcohols: DFT evidence of chemically non-innocent ligand participation

The acceptorless dehydrogenative coupling (ADC) of primary alcohols to esters by diazabutadiene-coordinated ruthenium compounds is reported. Treatment of cis-Ru(dmso)(4)Cl(2) in acetone at 56 °C with different 1,4-diazabutadienes [p-XC(6)H(4)N[double bond, length as m-dash]C(H)(H)C[double bond, leng...

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Detalles Bibliográficos
Autores principales:	Mukherjee, Aparajita, Datta, Sayanti, Richmond, Michael G., Bhattacharya, Samaresh
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463240/ https://www.ncbi.nlm.nih.gov/pubmed/37649575 http://dx.doi.org/10.1039/d3ra04750d

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