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Hydrogen bonding to oxygen in siloxane bonds drives liquid phase adsorption of primary alcohols in high-silica zeolites

Upon liquid phase adsorption of C(1)–C(5) primary alcohols on high silica MFI zeolites (Si/Al = 11.5–140), the concentration of adsorbed molecules largely exceeds the concentration of traditional adsorption sites: Brønsted acid and defect sites. Combining quantitative in situ(1)H MAS NMR, qualitativ...

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Detalles Bibliográficos
Autores principales: Radhakrishnan, Sambhu, Lejaegere, Charlotte, Duerinckx, Karel, Lo, Wei-Shang, Morais, Alysson F., Dom, Dirk, Chandran, C. Vinod, Hermans, Ive, Martens, Johan A., Breynaert, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10463557/
https://www.ncbi.nlm.nih.gov/pubmed/37401863
http://dx.doi.org/10.1039/d3mh00888f