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Triplet sensitization enables bidirectional isomerization of diazocine with 130 nm redshift in excitation wavelengths

Diazocines are bridged azobenzenes with phenyl rings connected by a CH(2)–CH(2) group. Despite this rather small structural difference, diazocine exhibits improved properties over azobenzene as a photoswitch and most importantly, its Z configuration is more stable than the E isomer. Herein, we revea...

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Detalles Bibliográficos
Autores principales: Isokuortti, Jussi, Griebenow, Thomas, von Glasenapp, Jan-Simon, Raeker, Tim, Filatov, Mikhail A., Laaksonen, Timo, Herges, Rainer, Durandin, Nikita A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466275/
https://www.ncbi.nlm.nih.gov/pubmed/37655019
http://dx.doi.org/10.1039/d3sc02681g