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Triplet sensitization enables bidirectional isomerization of diazocine with 130 nm redshift in excitation wavelengths
Diazocines are bridged azobenzenes with phenyl rings connected by a CH(2)–CH(2) group. Despite this rather small structural difference, diazocine exhibits improved properties over azobenzene as a photoswitch and most importantly, its Z configuration is more stable than the E isomer. Herein, we revea...
Autores principales: | Isokuortti, Jussi, Griebenow, Thomas, von Glasenapp, Jan-Simon, Raeker, Tim, Filatov, Mikhail A., Laaksonen, Timo, Herges, Rainer, Durandin, Nikita A. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466275/ https://www.ncbi.nlm.nih.gov/pubmed/37655019 http://dx.doi.org/10.1039/d3sc02681g |
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