Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation

The alumole Cp(3t)AlC(4)Et(4) (Cp(3t) = 1,2,4-tris(tert-butyl)cyclopentadienyl) is reported to be capable of transferring its butadiene moiety to aryl(dihalo)boranes to generate boroles through aluminum–boron exchange. The products feature a rare alkyl-substituted backbone, which, as shown in other...

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Detalles Bibliográficos
Autores principales: Bohlen, Josina L., Endres, Lukas, Drescher, Regina, Radacki, Krzysztof, Dietz, Maximilian, Krummenacher, Ivo, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466280/
https://www.ncbi.nlm.nih.gov/pubmed/37655034
http://dx.doi.org/10.1039/d3sc02668j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466280/
https://www.ncbi.nlm.nih.gov/pubmed/37655034
http://dx.doi.org/10.1039/d3sc02668j

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