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Boroles from alumoles: accessing boroles with alkyl-substituted backbones via transtrielation
The alumole Cp(3t)AlC(4)Et(4) (Cp(3t) = 1,2,4-tris(tert-butyl)cyclopentadienyl) is reported to be capable of transferring its butadiene moiety to aryl(dihalo)boranes to generate boroles through aluminum–boron exchange. The products feature a rare alkyl-substituted backbone, which, as shown in other...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466280/ https://www.ncbi.nlm.nih.gov/pubmed/37655034 http://dx.doi.org/10.1039/d3sc02668j |