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Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic Ni(II), Pd(II) and Pt(II) tetrathiolate bridges
Reaction of the nitrosylated-iron metallodithiolate ligand, paramagnetic (NO)Fe(N(2)S(2)), with [M(CH(3)CN)(n)][BF(4)](2) salts (M = Ni(II), Pd(II), and Pt(II); n = 4 or 6) affords di-radical tri-metallic complexes in a stairstep type arrangement ([FeMFe](2+), M = Ni, Pd, and Pt), with the central g...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466285/ https://www.ncbi.nlm.nih.gov/pubmed/37655023 http://dx.doi.org/10.1039/d3sc01546g |