Magnetic coupling between Fe(NO) spin probe ligands through diamagnetic Ni(II), Pd(II) and Pt(II) tetrathiolate bridges

Reaction of the nitrosylated-iron metallodithiolate ligand, paramagnetic (NO)Fe(N(2)S(2)), with [M(CH(3)CN)(n)][BF(4)](2) salts (M = Ni(II), Pd(II), and Pt(II); n = 4 or 6) affords di-radical tri-metallic complexes in a stairstep type arrangement ([FeMFe](2+), M = Ni, Pd, and Pt), with the central g...

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Detalles Bibliográficos
Autores principales: Quiroz, Manuel, Lockart, Molly M., Xue, Shan, Jones, Dakota, Guo, Yisong, Pierce, Brad S., Dunbar, Kim R., Hall, Michael B., Darensbourg, Marcetta Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466285/
https://www.ncbi.nlm.nih.gov/pubmed/37655023
http://dx.doi.org/10.1039/d3sc01546g

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