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Metal-free reductive desulfurization of C-sp(3)-substituted thiols using phosphite catalysis

Phosphines and phosphites are critical tools for non-metal desulfurative methodologies due to the strength of the P[double bond, length as m-dash]S bond. An overarching premise in these methods has been that stoichiometric (or excess) P(iii) reagent is required for reactivity. Despite decades of res...

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Detalles Bibliográficos
Autores principales: Morsy, Rana M. I., Samala, Ganesh, Jalan, Ankur, Kopach, Michael E., Venneti, Naresh M., Stockdill, Jennifer L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466286/
https://www.ncbi.nlm.nih.gov/pubmed/37655042
http://dx.doi.org/10.1039/d3sc00045a