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Confinement inside MOFs Enables Guest-Modulated Spin Crossover of Otherwise Low-Spin Coordination Cages

[Image: see text] Confinement of discrete coordination cages within nanoporous lattices is an intriguing strategy to gain unusual properties and functions. We demonstrate here that the confinement of coordination cages within metal–organic frameworks (MOFs) allows the spin state of the cages to be r...

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Detalles Bibliográficos
Autores principales: Yang, Shuai-Liang, Zhang, Xiang, Wang, Qing, Wu, Chao, Liu, Haiming, Jiang, Dongmei, Lavendomme, Roy, Zhang, Dawei, Gao, En-Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10466325/
https://www.ncbi.nlm.nih.gov/pubmed/37654592
http://dx.doi.org/10.1021/jacsau.3c00243