Mechanism Insights into the Iridium(III)- and B(C(6)F(5))(3)-Catalyzed Reduction of CO(2) to the Formaldehyde Level with Tertiary Silanes

[Image: see text] The catalytic system [Ir(CF(3)CO(2))(κ(2)-NSi(Me))(2)] [1; NSi(Me) = (4-methylpyridin-2-yloxy)dimethylsilyl]/B(C(6)F(5))(3) promotes the selective reduction of CO(2) with tertiary silanes to the corresponding bis(silyl)acetal. Stoichiometric and catalytic studies evidenced that spe...

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Detalles Bibliográficos
Autores principales: Guzmán, Jefferson, Urriolabeitia, Asier, Padilla, Marina, García-Orduña, Pilar, Polo, Víctor, Fernández-Alvarez, Francisco J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468102/
https://www.ncbi.nlm.nih.gov/pubmed/36472385
http://dx.doi.org/10.1021/acs.inorgchem.2c03330

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468102/
https://www.ncbi.nlm.nih.gov/pubmed/36472385
http://dx.doi.org/10.1021/acs.inorgchem.2c03330

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