Synthesis and Characterization of Ir-(κ(2)-NSi) Species Active toward the Solventless Hydrolysis of HSiMe(OSiMe(3))(2)

[Image: see text] The reaction of [IrH(Cl)(κ(2)-NSi(tBu2))(coe)] (1) with 1 equiv of PCy(3) (or PH(t)Bu(2)) gives the species [IrH(Cl)(κ(2)-NSi(tBu2))(L)] (L = PCy(3), 2a; PH(t)Bu(2), 2b), which reacts with 1 equiv of AgOTf to afford [IrH(OTf)(κ(2)-NSi(tBu2))(L)] (L = PCy(3), 3a and PH(t)Bu(2), 3b)....

Descripción completa

Detalles Bibliográficos
Autores principales: Gómez-España, Alejandra, García-Orduña, Pilar, Guzmán, Jefferson, Fernández, Israel, Fernández-Alvarez, Francisco J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468103/
https://www.ncbi.nlm.nih.gov/pubmed/36194856
http://dx.doi.org/10.1021/acs.inorgchem.2c01973

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468103/
https://www.ncbi.nlm.nih.gov/pubmed/36194856
http://dx.doi.org/10.1021/acs.inorgchem.2c01973

Ejemplares similares