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Synthesis and Characterization of Ir-(κ(2)-NSi) Species Active toward the Solventless Hydrolysis of HSiMe(OSiMe(3))(2)
[Image: see text] The reaction of [IrH(Cl)(κ(2)-NSi(tBu2))(coe)] (1) with 1 equiv of PCy(3) (or PH(t)Bu(2)) gives the species [IrH(Cl)(κ(2)-NSi(tBu2))(L)] (L = PCy(3), 2a; PH(t)Bu(2), 2b), which reacts with 1 equiv of AgOTf to afford [IrH(OTf)(κ(2)-NSi(tBu2))(L)] (L = PCy(3), 3a and PH(t)Bu(2), 3b)....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468103/ https://www.ncbi.nlm.nih.gov/pubmed/36194856 http://dx.doi.org/10.1021/acs.inorgchem.2c01973 |