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Locating Interstitial Hydrides in MH(2)@Cu(14) (M = Cu, Ag) Clusters by Single-Crystal X-ray Diffraction

[Image: see text] Two structures, [Cu(15)H(2)(S(2)CN(n)Bu(2))(6)(C≡CPh)(6)][CuCl(2)] (1) and [AgH(2)Cu(14){S(2)P(O(i)Pr)(2)}(6)(C≡CPh)(6)][PF(6)] (2), are characterized by X-ray crystallography with high-quality single crystals. The position of interstitial hydrides can be accurately located. In add...

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Detalles Bibliográficos
Autores principales: Liao, Jian-Hong, Brocha Silalahi, Rhone P., Chiu, Tzu-Hao, Liu, C. W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468881/
https://www.ncbi.nlm.nih.gov/pubmed/37663474
http://dx.doi.org/10.1021/acsomega.3c04758