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Locating Interstitial Hydrides in MH(2)@Cu(14) (M = Cu, Ag) Clusters by Single-Crystal X-ray Diffraction
[Image: see text] Two structures, [Cu(15)H(2)(S(2)CN(n)Bu(2))(6)(C≡CPh)(6)][CuCl(2)] (1) and [AgH(2)Cu(14){S(2)P(O(i)Pr)(2)}(6)(C≡CPh)(6)][PF(6)] (2), are characterized by X-ray crystallography with high-quality single crystals. The position of interstitial hydrides can be accurately located. In add...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10468881/ https://www.ncbi.nlm.nih.gov/pubmed/37663474 http://dx.doi.org/10.1021/acsomega.3c04758 |