Dynamic and Persistent Cyclochirality in Hydrogen-Bonded Derivatives of Medium-Ring Triamines

[Image: see text] Cyclic triureas derived from 1,4,7-triazacyclononane (TACN) were synthesized; X-ray crystallography showed a chiral bowl-like conformation with each urea hydrogen-bonded to its neighbor with uniform directionality, forming a “cyclochiral” closed loop of hydrogen bonds. Variable-tem...

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Detalles Bibliográficos
Autores principales: Morris, David T. J., Wales, Steven M., Echavarren, Javier, Žabka, Matej, Marsico, Giulia, Ward, John W., Pridmore, Natalie E., Clayden, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10472504/
https://www.ncbi.nlm.nih.gov/pubmed/37594473
http://dx.doi.org/10.1021/jacs.3c06570

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10472504/
https://www.ncbi.nlm.nih.gov/pubmed/37594473
http://dx.doi.org/10.1021/jacs.3c06570

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