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Acceptorless cross-dehydrogenative coupling for C(sp(3))-H heteroarylation mediated by a heterogeneous GaN/ketone photocatalyst/photosensitizer system

Alkanes are naturally abundant chemical building blocks that contain plentiful C(sp(3))-H bonds. While inert, the activation of C(sp(3))-H via hydrogen atom abstraction (HAT) stages an appealing approach to generate alkyl radicals. However, prevailing shortcomings include the excessive use of oxidan...

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Detalles Bibliográficos
Autores principales: Kang, Hyotaik, Tan, Lida, Han, Jing-Tan, Huang, Chia-Yu, Su, Hui, Kavun, Aleksei, Li, Chao-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10474291/
https://www.ncbi.nlm.nih.gov/pubmed/37658203
http://dx.doi.org/10.1038/s42004-023-00947-w