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Acceptorless cross-dehydrogenative coupling for C(sp(3))-H heteroarylation mediated by a heterogeneous GaN/ketone photocatalyst/photosensitizer system
Alkanes are naturally abundant chemical building blocks that contain plentiful C(sp(3))-H bonds. While inert, the activation of C(sp(3))-H via hydrogen atom abstraction (HAT) stages an appealing approach to generate alkyl radicals. However, prevailing shortcomings include the excessive use of oxidan...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10474291/ https://www.ncbi.nlm.nih.gov/pubmed/37658203 http://dx.doi.org/10.1038/s42004-023-00947-w |