Pre-electrolysis of LiClO(4) in Acetonitrile: Electrochemically Induced Protolytic Carbon–Carbon Bond Formation of Benzylic Ethers and Acetals with Allyl Trimethylsilane and Other Carbon Nucleophiles

[Image: see text] The pre-electrolysis of LiClO(4) in acetonitrile in an undivided cell applying only “catalytic” amounts of current (e.g., 0.05 F) led to the formation of a strong acidic medium for the activation of benzylic ethers and acetals. The activated primary and secondary benzylic ethers an...

Descripción completa

Detalles Bibliográficos
Autores principales: Fastie, Cornelius, Li, Luomo, Bätcher, Moritz, Hilt, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476155/
https://www.ncbi.nlm.nih.gov/pubmed/37594465
http://dx.doi.org/10.1021/acs.joc.3c01256

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476155/
https://www.ncbi.nlm.nih.gov/pubmed/37594465
http://dx.doi.org/10.1021/acs.joc.3c01256

Ejemplares similares