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Probing Catalyst Degradation in Metathesis of Internal Olefins: Expanding Access to Amine-Tagged ROMP Polymers

[Image: see text] Ruthenium-promoted ring-opening metathesis polymerization (ROMP) offers potentially powerful routes to amine-functionalized polymers with antimicrobial, adhesive, and self-healing properties. However, amines readily degrade the methylidene and unsubstituted ruthenacyclobutane inter...

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Detalles Bibliográficos
Autores principales: Cormier, Samantha K., Fogg, Deryn E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476157/
https://www.ncbi.nlm.nih.gov/pubmed/37671179
http://dx.doi.org/10.1021/acscatal.3c02729