An NHC-Catalyzed Desulfonylative Smiles Rearrangement of Pyrrole and Indole Carboxaldehydes

[Image: see text] The use of catalysis methods to enable Smiles rearrangement opens up new substrate classes for arylation under mild conditions. Here, we describe an N-heterocyclic carbene (NHC) catalysis system that accesses indole and pyrrole aldehyde substrates in a desulfonylative Smiles proces...

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Detalles Bibliográficos
Autores principales: Swaby, Caitlin, Taylor, Alfie, Greaney, Michael F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476196/
https://www.ncbi.nlm.nih.gov/pubmed/37589318
http://dx.doi.org/10.1021/acs.joc.3c01089

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476196/
https://www.ncbi.nlm.nih.gov/pubmed/37589318
http://dx.doi.org/10.1021/acs.joc.3c01089

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