Aryl versus Alkyl Redox-Active Diazoacetates — Light-Induced C–H Insertion or 1,2-Rearrangement

[Image: see text] Diazo compounds with redox-active leaving groups are versatile reagents for orthogonal functionalizations, previously utilized in the Rh-catalyzed synthesis of highly substituted cyclopropanes. Photochemical activation of aryl-substituted diazoacetates generates carbenes, whereas r...

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Detalles Bibliográficos
Autores principales: Santiago, João V., Orłowska, Katarzyna, Ociepa, Michał, Gryko, Dorota
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476266/
https://www.ncbi.nlm.nih.gov/pubmed/37607356
http://dx.doi.org/10.1021/acs.orglett.3c02055

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10476266/
https://www.ncbi.nlm.nih.gov/pubmed/37607356
http://dx.doi.org/10.1021/acs.orglett.3c02055

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