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Axial vs equatorial: Capturing the intramolecular charge transfer state geometry in conformational polymorphic crystals of a donor–bridge–acceptor dyad in nanosecond-time-scale

Two conformational polymorphs of a donor–bridge–acceptor (D-B-A) dyad, p-(CH(3))(2)N-C(6)H(4)-(CH(2))(2)-(1-pyrenyl)/PyCHDMA, were studied, where the electron donor (D) moiety p-(CH(3))(2)N-C(6)H(4)/DMA is connected through a bridging group (B), –CH(2)–CH(2)–, to the electron acceptor (A) moiety pyr...

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Detalles Bibliográficos
Autores principales: Basuroy, Krishnayan, Velazquez-Garcia, Jose de J., Storozhuk, Darina, Henning, Robert, Gosztola, David J., Thekku Veedu, Sreevidya, Techert, Simone
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AIP Publishing LLC 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10481388/
https://www.ncbi.nlm.nih.gov/pubmed/36754826
http://dx.doi.org/10.1063/5.0134792