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Effects of Methyl Substitution and Leaving Group on E2/S(N)2 Competition for Reactions of F(−) with RY (R = CH(3), C(2)H(5), (i)C(3)H(7), (t)C(4)H(9); Y = Cl, I)
The competition between base-induced elimination (E2) and bimolecular nucleophilic substitution (S(N)2) is of significant importance in organic chemistry and is influenced by many factors. The electronic structure calculations for the gas-phase reactions of F(−) + RY (R = CH(3), C(2)H(5), (i)C(3)H(7...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10488877/ https://www.ncbi.nlm.nih.gov/pubmed/37687098 http://dx.doi.org/10.3390/molecules28176269 |