Cargando…

Effects of Methyl Substitution and Leaving Group on E2/S(N)2 Competition for Reactions of F(−) with RY (R = CH(3), C(2)H(5), (i)C(3)H(7), (t)C(4)H(9); Y = Cl, I)

The competition between base-induced elimination (E2) and bimolecular nucleophilic substitution (S(N)2) is of significant importance in organic chemistry and is influenced by many factors. The electronic structure calculations for the gas-phase reactions of F(−) + RY (R = CH(3), C(2)H(5), (i)C(3)H(7...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zhen, Wenqing, Zhao, Siwei, Fu, Gang, Wang, Hongyi, Sun, Jianmin, Yang, Li, Zhang, Jiaxu
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10488877/ https://www.ncbi.nlm.nih.gov/pubmed/37687098 http://dx.doi.org/10.3390/molecules28176269

Ejemplares similares

Imaging Reaction Dynamics of F(–)(H(2)O) and Cl(–)(H(2)O) with CH(3)I
por: Bastian, Björn, et al.
Publicado: (2020)

Syntheses and crystal structures of [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}ClH]Cl·2.75CH(2)Cl(2) and its derivatives, [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}(CH(2)CO(2)Et)Cl]Cl·CH(3)OH·0.5H(2)O, [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}Cl(2)]Cl·CH(3)OH·2H(2)O and [Ir(III){C(CHCO(2)Et)(dppm)(2)-κ(4) P,C,C′,P′}(CH(2)CO(2)Et)(CO)]Cl(2)·2CH(2)Cl(2)·1.5H(2)O
por: Schlapp-Hackl, Inge, et al.
Publicado: (2019)

Up-Scale Synthesis of p-(CH(2)=CH)C(6)H(4)CH(2)CH(2)CH(2)Cl and p-ClC(6)H(4)SiR(3) by CuCN-Catalyzed Coupling Reactions of Grignard Reagents with Organic Halides
por: Park, Ju Yong, et al.
Publicado: (2022)

Is It Conjugated or Not? The Theoretical and Experimental Electron Density Map of Bonding in p-CH(3)CH(2)COC(6)H(4)-C≡C-C≡C-p-C(6)H(4)COCH(3)CH(2)
por: Starynowicz, Przemysław, et al.
Publicado: (2020)

Broadening of the ν(2) Raman Band of CH(4) by C(3)H(8) and C(4)H(10)
por: Tanichev, Aleksandr S., et al.
Publicado: (2023)

Cation dynamics by (1)H and (13)C MAS NMR in hybrid organic–inorganic (CH(3)CH(2)NH(3))(2)CuCl(4)
por: Lim, Ae Ran, et al.
Publicado: (2018)

Rotational Mode-Specificity in the Cl + C(2)H(6) → HCl + C(2)H(5) Reaction
por: Papp, Dóra, et al.
Publicado: (2022)

Crystal structures of [Li(7)(i-PrO)(3)(C(4)H(10)NO)(3)](2)O and [Na(i-PrOH)(2)(C(8)H(18)NO(2))](2)
por: Scheel, Rebecca, et al.
Publicado: (2020)

Structural Study of the Compounds Formed in the Reactions of FeCl(3)·6H(2)O with Ni(OH)(2) in the Presence of Dithiolenes HSRSH (R = C(6)H(2)Cl(2) or C(6)H(4))
por: Delgado, Esther, et al.
Publicado: (2020)

Histocompatibility antigens controlled by the I region of the murine H- 2 complex. I. Mapping of H-2A and H-2C loci
Publicado: (1976)

Synergistic effects of CH(3)CO(2)H and Ca(2+) on C–H bond activation by MnO(4)(−)
por: Shi, Huatian, et al.
Publicado: (2022)

Unusual Complexes of P(CH)(3) with FH, ClH, and ClF
por: Del Bene, Janet E., et al.
Publicado: (2020)

An Experimental and Master Equation Investigation of Kinetics of the CH(2)OO + RCN Reactions (R = H, CH(3), C(2)H(5)) and Their Atmospheric Relevance
por: Franzon, Lauri, et al.
Publicado: (2023)

The Chloronium Cation [(C(2)H(3))(2)Cl(+)] and Unsaturated C(4)-Carbocations with C=C and C≡C Bonds in Their Solid Salts and in Solutions: An H(1)/C(13) NMR and Infrared Spectroscopic Study
por: Stoyanov, Evgenii S., et al.
Publicado: (2022)

Synthesis and crystal structure of [Pd{C(6)H(4)(CH(2)NHCH(2)Ph)-2-κ(2) C,N}(μ-I)](2)
por: Bautista, Delia, et al.
Publicado: (2017)

Collision-induced and complex-mediated roaming dynamics in the H + C(2)H(4) → H(2) + C(2)H(3) reaction
por: Fu, Yan-Lin, et al.
Publicado: (2020)

Profile of Spencer C.H. Barrett
por: Azar, Beth
Publicado: (2023)

Ruddlesden–Popper 2D perovskites of type (C(6)H(9)C(2)H(4)NH(3))(2)(CH(3)NH(3))(n−1)Pb(n)I(3n+1) (n = 1–4) for optoelectronic applications
por: Rahil, Mohammad, et al.
Publicado: (2022)

Dynamics and fragmentation mechanism of (C(5)H(4)CH(3))Pt(CH(3))(3) on SiO(2) surfaces
por: Muthukumar, Kaliappan, et al.
Publicado: (2018)

Direct Measurement of Radical-Catalyzed C(6)H(6) Formation from Acetylene and Validation of Theoretical Rate Coefficients for C(2)H(3) + C(2)H(2) and C(4)H(5) + C(2)H(2) Reactions
por: Smith, Mica C., et al.
Publicado: (2020)

Synthesis, Structural, Linear, and Nonlinear Optical Studies of Inorganic–Organic Hybrid Semiconductors (R–C(6)H(4)CHCH(3)NH(3))(2)PbI(4), (R = CH(3), Cl)
por: Adnan, Mohammad, et al.
Publicado: (2019)

VUV Photofragmentation of Chloroiodomethane: The Iso-CH(2)I–Cl and Iso-CH(2)Cl–I Radical Cation Formation
por: Casavola, Anna Rita, et al.
Publicado: (2020)

The Phospha–Michael addition product {(t-BuNH)P(μ-N-t-Bu)(2)P(=N-t-Bu)—C(=CH(2))CH(p-CH(3)O—C(6)H(4))-P(O)[(OCH(2)C(CH(3))(2)CH(2)O)]}
por: Gangadhararao, G., et al.
Publicado: (2011)

Experimental Investigation of the Impact of CO, C(2)H(6), and H(2) on the Explosion Characteristics of CH(4)
por: Wang, Hua, et al.
Publicado: (2020)

Studies on the Kinetics of the CH + H(2) Reaction and Implications for the Reverse Reaction, (3)CH(2) + H
por: Blitz, Mark A., et al.
Publicado: (2023)

Crystal structures of [IrCl(2)(NHCHPh)((dppm)(C(N(2)dppm))-κ(3) P,C,P′)]Cl·5.5MeCN and [IrI(NHCHPh)(((dppm)C(N(2)))-κ(2) P,C)(dppm-κ(2) P,P′)]I(I(3))·0.5I(2)·MeOH·0.5CH(2)Cl(2): triazene fragmentation in a PCN pincer iridium complex
por: Pauer, Bettina, et al.
Publicado: (2019)

The Coordination Behavior of Two New Complexes, [(C(7)H(10)NO(2))CdCl(3)](n)(I) and [(C(7)H(9)NO(2))CuCl(2)] (II), Based on 2,6-Dimethanolpyridine; Elaboration of the Structure and Hirshfeld Surface, Optical, Spectroscopic and Thermal Analysis
por: Hermi, Sabrine, et al.
Publicado: (2022)

Crystal structure of (C(9)H(17)N(2))(3)[Bi(2)I(9)]
por: James, Zoe, et al.
Publicado: (2021)

Synthesis, X-ray diffraction and Hirshfeld surface analysis of two new hybrid dihydrate compounds: (C(6)H(22)N(4))[SnCl(6)]Cl(2)·2H(2)O and (C(8)H(24)N(4))[SnCl(6)]Cl(2)·2H(2)O
por: Bouchene, Rafika, et al.
Publicado: (2018)

The CENP-T C-Terminus Is Exclusively Proximal to H3.1 and not to H3.2 or H3.3
por: Abendroth, Christian, et al.
Publicado: (2015)

Mechanistic and Kinetic Approach on the Propargyl Radical (C(3)H(3)) with the Criegee Intermediate (CH(2)OO)
por: Pham, Tien V., et al.
Publicado: (2023)

Combined multilepton and diphoton limit on t to cH
por: CMS Collaboration
Publicado: (2014)

Ligand-Promoted Alkylation of C(sp(3))–H and C(sp(2))–H Bonds
por: Zhu, Ru-Yi, et al.
Publicado: (2014)

Standard molar enthalpy of combustion and formation of quaternary ammonium tetrachlorozincate [n-C(n)H(2n+1) N(CH(3))(3)](2) ZnCl(4)
por: Ren, Biyan, et al.
Publicado: (2013)

Activation of Small Molecules (H(2), CO(2), N(2)O, CH(4), and C(6)H(6)) by a Porphyrinoid-Based Dimagnesium(I) Complex, an Electride
por: Saha, Ranajit, et al.
Publicado: (2018)

Electron-Impact Total Ionization Cross Sections of CH and C(2)H(2)
por: Kim, Yong-Ki, et al.
Publicado: (1997)

Photodissociation of aligned CH(3)I and C(6)H(3)F(2)I molecules probed with time-resolved Coulomb explosion imaging by site-selective extreme ultraviolet ionization
por: Amini, Kasra, et al.
Publicado: (2018)

The Varied Frustrated Lewis Pair Reactivity of the Germylene Phosphaketene (CH{(CMe)(2,6‐( i )Pr(2)C(6)H(3)N)}(2))GePCO
por: Wu, Yile, et al.
Publicado: (2022)

Sensing the ortho Positions in C(6)Cl(6) and C(6)H(4)Cl(2) from Cl(2)(−) Formation upon Molecular Reduction
por: Kumar, Sarvesh, et al.
Publicado: (2022)

Three-dimensional organic–inorganic hybrid sodium halide perovskite: C(4)H(12)N(2)·NaI(3) and a hydrogen-bonded supramolecular three-dimensional network in 3C(4)H(12)N(2)·NaI(4)·3I·H(2)O
por: Chen, Xiao-Gang, et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_hr4qcff66k5qi2jpqmp99mr2i9