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The Synthesis and Base-Induced Breakdown of Triaryl 1,4-Oxathiins—An Experimental and DFT Study

1,4-Oxathiins are valued for a breadth of bioactivities and are known commercial fungicides. This article explores a novel preparation of 2,3,6-trisubstituted 1,4-oxathiin-S,S-dioxides via the reaction of benzyl 1-alkynyl sulfones and aryl aldehydes under basic conditions. A total of 20 examples pos...

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Detalles Bibliográficos
Autores principales: Nicol, Eric A., Sing, Matthew, Luu, Lilly U., Remigio, Erwin J., Mills, Michelle B., Schwan, Adrian L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10489040/
https://www.ncbi.nlm.nih.gov/pubmed/37687009
http://dx.doi.org/10.3390/molecules28176180