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Evidence of bifunctionality of carbons and metal atoms in catalyzed acetylene hydrochlorination

Carbon supports are ubiquitous components of heterogeneous catalysts for acetylene hydrochlorination to vinyl chloride, from commercial mercury-based systems to more sustainable metal single-atom alternatives. Their potential co-catalytic role has long been postulated but never unequivocally demonst...

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Detalles Bibliográficos
Autores principales: Giulimondi, Vera, Ruiz-Ferrando, Andrea, Giannakakis, Georgios, Surin, Ivan, Agrachev, Mikhail, Jeschke, Gunnar, Krumeich, Frank, López, Núria, Clark, Adam H., Pérez-Ramírez, Javier
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10492806/
https://www.ncbi.nlm.nih.gov/pubmed/37689779
http://dx.doi.org/10.1038/s41467-023-41344-0